N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate
نویسندگان
چکیده
In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methyl-idenehydrazide fragment, which is fully extended with C-C-N-N, C-N-N=C and N-N=C-C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the water of hydration is involved in extensive hydrogen bonding. Inter-molecular O-H⋯O, N-H⋯O and O-H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak inter-molecular C-H⋯O hydrogen bonds.
منابع مشابه
4-Bromo-N-[4-(diethylamino)benzylidene]aniline
The asymmetric unit of the title compound, C(17)H(19)BrN(2), contains two independent mol-ecules. The dihedral angles between the two benzene rings in are 60.4 (2) and 61.0 (2)°.
متن کامل4-Chloro-N-[4-(diethylamino)benzylidene]aniline
The asymmetric unit of the title compound, C(17)H(19)ClN(2), contains two independent mol-ecules which differ by a 180° flip in the orientation of the 4-chloro-aniline unit with respect to the diethyl-amino-benzyl-idene unit [N=C-C-C = 10.0 (3) and -170.6 (2)°]. The dihedral angles between the two aromatic rings are 64.0 (1) and 66.5 (1)° in the two independent mol-ecules.
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In the title compound, C(15)H(13)N(3)O(3)·H(2)O, the two benzene rings form a dihedral angle of 2.03 (2)°. In the crystal structure, adjacent hydrazide mol-ecules are linked into dimers by water mol-ecules; these dimers are then stacked along the b axis. Inter-molecular O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds and a π-π stacking inter-action between the nitro-benzene and tolyl rings with a centroi...
متن کاملDiethyl 2-{4-diethylamino-2-[(dimethylcarbamothioyl)oxy]benzylidene}malonate
In the title compound, C(21)H(30)N(2)O(5)S, the plane of the dimeth-yl-thio-carbamic group makes a dihedral angle of 78.41 (7)° with the central benzene ring. One of the carbonyl groups in the α,β-unsaturated malonate side chain makes a dihedral angle of 8.73 (10)° with the central benzene ring, while the other carbonyl group makes a dihedral angle of 81.52 (8)°.
متن کاملN′-(3-Methoxybenzylidene)-4-nitrobenzohydrazide monohydrate
There are two independent formula units in the asymmetric unit of the title compound, C(15)H(13)N(3)O(4)·H(2)O. The C=C-N-C torsion angle of the methyl-idenehydrazide group is 174.3 (2)° in one mol-ecule and 178.6 (2)° in the other. The dihedral angles between the two benzene rings in the two mol-ecules are 4.17 (12) and 3.58 (12)°. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O and O-H...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010